Bacterial polyesters: biosynthesis, biodegradable plastics and biotechnology

RW Lenz, RH Marchessault - Biomacromolecules, 2005 - ACS Publications
The discovery and chemical identification, in the 1920s, of the aliphatic polyester: poly(3-hydroxybutyrate),
PHB, as a granular component in bacterial cells proceeded without any of the …

Polyester-based micelles and nanoparticles for the parenteral delivery of taxanes

G Gaucher, RH Marchessault, JC Leroux - Journal of controlled release, 2010 - Elsevier
Taxanes are potent antimitotic agents that have demonstrated efficacy in a wide range of
malignancies. Due to their poor water-solubility, these cytostatic drugs were first formulated with …

Cross-linked high amylose starch for controlled release of drugs: recent advances

…, MA Mateescu, L Cartilier, R Marchessault - Journal of controlled …, 1998 - Elsevier
Cross-linked high amylose starches have been developed as excipients for the formulation
of controlled-release solid dosage forms for the oral delivery of drugs. Advantages of this …

Helicoidal self-ordering of cellulose microfibrils in aqueous suspension

…, H Bradford, J Giasson, RH Marchessault… - International journal of …, 1992 - Elsevier
In many skeletal support systems of plants and animals, cellulose, chitin, and collagen occur
in the form of microfibrils ordered in a chiral nematic fashion (helicoids). However, these …

Liquid crystal systems from fibrillar polysaccharides

RH Marchessault, FF Morehead, NM Walter - Nature, 1959 - nature.com
THE preparation of a neutral aqueous suspension of cellulose crystallites by hydrolysis in
strong sulphuric acid (952 gm./l.) at 30 or 40 C. for 24 hr. has been described 1 . A similar …

Crystal structure of poly-ε-caprolactone

H Bittiger, RH Marchessault… - … Section B: Structural …, 1970 - scripts.iucr.org
The unit cell of poly-e-caprolactone was found to be orthorhombic with dimensions a= 7.496+
0.002, b= 4.974+ 0" 001, c= 17.297+ 0-023/~(fiber axis). The space group is P212121. …

Infrared spectra of crystalline polysaccharides. I. Hydrogen bonds in native celluloses

CY Liang, RH Marchessault - Journal of polymer science, 1959 - Wiley Online Library
The infrared spectra of oriented films of valonia cellulose and of ramie and bacterial cellulose
crystallites have been observed in the 3 μ region. Polarization properties of the bands …

Infrared spectra of crystalline polysaccharides. V. Chitin

FG Pearson, RH Marchessault… - Journal of Polymer …, 1960 - Wiley Online Library
The polarized infrared spectra of crab chitin crystallites, blowfly larval cuticle, lobster tendon,
and partially deacetylated lobster chitin have been studied. In addition, the spectra of …

Studies of composition and crystallinity of bacterial poly (β-hydroxybutyrate-co-β-hydroxyvalerate)

…, GK Hamer, TL Bluhm, RH Marchessault - …, 1986 - ACS Publications
Samples of bacterial poly (d-hydroxybutyrate-co-fl-hydroxyvalerate)(P (HB-co-HV)) were
analyzed by 250-MHz 1H nuclear magnetic resonance(NMR) and Fourier transforminfrared (…

In vitro chiral nematic ordering of chitin crystallites

JF Revol, RH Marchessault - International journal of biological …, 1993 - Elsevier
Microfibrillar fragments of purified crab and shrimp chitin were prepared by hydrolysis in 3 m
HCl at its boiling point (104C). After removal of the acid by centrifugal washing and dialysis, …